Thermal- and Photo-Polymerization of Epoxy and Acrylate Monomers with N-Methylammonium Salts
نویسندگان
چکیده
منابع مشابه
Study the curing behavior and mechanical properties of Pigmented UV curable epoxy acrylate monomers
The formulations contained different acrylate monomer with different structure and functionalities and TiO2, were applied to obtain pigmented acrylic films by UV exposure. The conversion and mechanical characteristic were correlated. The results showed that there is a significant interaction between pigment, reactive diluents’ type and mechanical properties of coatings. It seems that cured film...
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In this study, the mechanism of self-initiation in spontaneous thermal polymerization of ethyl and n-butyl acrylate is explored using first-principles calculations. Density functional theory (with B3LYP functional and 6-31G* basis set) was used to study [4 + 2] and [2 + 2] cycloaddition reactions on the singlet and triplet potential energy surfaces. Diels-Alder (DA) dimers of ethyl acrylate [6-...
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15 صفحه اولOn the Thermal Self-Initiation Reaction of n-Butyl Acrylate in Free-Radical Polymerization
This experimental and theoretical study deals with the thermal spontaneous polymerization of n-butyl acrylate (n-BA). The polymerization was carried out in solution (n-heptane as the solvent) at 200 and 220 ◦C without adding any conventional initiators. It was studied with the five different n-BA/n-heptane volume ratios: 50/50, 70/30, 80/20, 90/10, and 100/0. Extensive experimental data present...
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ژورنال
عنوان ژورنال: Journal of The Adhesion Society of Japan
سال: 2002
ISSN: 0916-4812,2187-4816
DOI: 10.11618/adhesion.38.372